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Element 72 · Hafnium (Hf)

Hafnium Bohr model: diagram and electrons per shell

The hafnium Bohr model shows a hafnium atom (Hf) as a small nucleus with its electrons circling it in 6 shells: 2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P. This page has a rotating 3D hafnium Bohr model, a flat diagram, a table of the electrons in each shell and the steps to draw it yourself.

Rotate the hafnium Bohr model in 3D

Drag to orbit, scroll to zoom.

This is a Bohr model of hafnium (Hf), a simplified picture of a single hafnium atom. Its nucleus holds 72 protons, and a neutral hafnium atom has 72 electrons, arranged around it in 6 shells (2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P).

Hf K · 21s2 L · 82s2 2p6 M · 183s2 3p6 3d10 N · 324s2 4p6 4d10 4f14 O · 105s2 5p6 5d2 P · 26s2

Hafnium Bohr model diagram

Bohr model diagram of hafnium: a nucleus of 72 protons with 72 electrons on 6 shells, 2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P, each ring labelled with its shell letter.
The hafnium Bohr model drawn flat: each ring is a shell, labelled with its letter, and every dot is an electron (2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P).

Hafnium electrons per shell

A neutral hafnium atom has 72 electrons, one for each of its 72 protons. They fill the shells from the nucleus outwards: 2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P.

Electrons in each shell of the hafnium Bohr model
ShellShell number (n)ElectronsMost it can hold (2n²)Subshells
K1221s2
L2882s2 2p6
M318183s2 3p6 3d10
N432324s2 4p6 4d10 4f14
O510505s2 5p6 5d2
P62726s2

How the hafnium Bohr model builds up, shell by shell

Watch the hafnium Bohr model come together: the nucleus first, then each shell in turn, from the innermost outwards, with its electrons joining the ring. The legend names every shell and counts its electrons, so you can read off the arrangement (2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P) as it forms.

Animation of the hafnium Bohr model being built: a nucleus of 72 protons appears first, then each shell grows in around it and takes its electrons, giving 72 electrons on 6 shells (2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P).
The hafnium Bohr model built up in six seconds: the nucleus first, then each shell with its electrons, ending with 2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P. Protons are red, neutrons yellow and electrons blue.

How to draw the hafnium Bohr model

  1. Find the atomic number. Hafnium has atomic number 72, so a neutral atom has 72 protons and 72 electrons.
  2. Draw the nucleus. Put a circle in the centre and write Hf in it. The 72 protons sit there with the neutrons.
  3. Draw the shells. Sketch 6 shells as rings around the nucleus. A shell holds at most 2n² electrons: 2 in the first, 8 in the second, 18 in the third and 32 in the fourth.
  4. Place the electrons. Fill from the inside out: 2 in shell K, 8 in shell L, 18 in shell M, 32 in shell N, 10 in shell O and 2 in shell P.
  5. Check the total. 2 + 8 + 18 + 32 + 10 + 2 = 72, the atomic number, so every electron is accounted for.

Atomic data for the hafnium Bohr model

The numbers behind the hafnium Bohr model, grouped by topic. Radii are in picometres (pm) and energies in kilojoules per mole (kJ/mol).

Identity

Symbol
Hf
Atomic number
72
Atomic mass
178.492 u
Family
Transition Metals
Position
group 4, period 6
Block
d-block

Electron configuration

Full
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d2
Shorthand
[Xe] 4f14 5d2 6s2
Electrons per shell
2, 8, 18, 32, 10, 2
Outer-shell electrons
2 in shell P

Ionisation energies

I₁
658.5
I₂
1440
I₃
2250
I₄
3216

Energy to remove each electron in turn (kJ/mol). A sharp jump means the next electron comes from an inner shell.

Atomic radii

Calculated (pm)
208
Empirical (pm)
155
Covalent (pm)
152

Electronegativity and electron affinity

Electronegativity (Pauling)
1.3
Electron affinity (kJ/mol)
17.18

Oxidation states

+4

Charges the element commonly takes in compounds.

Physical properties, abundance and history of hafnium

Bulk properties of hafnium, how common it is, who discovered it and some of its compounds.

Physical properties

Phase at room conditions
Solid
Appearance
Steel gray
Melting point
2232.85°C (2506 K)
Boiling point
4602.85°C (4876 K)
Density
13.31 g/cm³
Thermal conductivity (W/m·K)
23
Specific heat (J/g·K)
0.144
Molar heat capacity (J/mol·K)
25.73
Heat of fusion (kJ/mol)
25.1
Heat of vaporisation (kJ/mol)
575

Abundance

Earth's crust (mg/kg)
3
Oceans (mg/L)
0

Discovery

Discovered by
Dirk Coster
Year
1923

Common compounds

  • Hafnium Hf
  • Hafnium oxide HfO2
  • Hafnium tetrachloride Cl4Hf
  • Hafnium tetrafluoride F4Hf
  • Hafnium chloride oxide (HfCl2O) Cl2H2HfO-2
  • Hafnium selenide (HfSe2) HfSe2
  • Sulfuric acid, hafnium(4+) salt (2:1) HfO8S2
  • Hafnium dihydride H2Hf-2

Compounds listed in the PubChem database.

Main isotopes of hafnium

Isotopes of hafnium share the same 72 protons but differ in neutrons. Natural isotopes come first, then the longest-lived others.

Main isotopes of hafnium: mass number, abundance, half-life and decay
Mass numberNatural abundanceHalf-lifeDecay
1740.16 %2 Pyα, 2β⁺
1765.26 %stable–
17718.6 %stable–
17827.28 %stable–
17913.62 %stable–
18035.08 %stable–

α = alpha decay, β⁻ = beta-minus, β⁺ = beta-plus, EC = electron capture, SF = spontaneous fission, p / n = proton / neutron emission.

More about hafnium